Showing posts with label Oxidation. Show all posts
Showing posts with label Oxidation. Show all posts

Monday, March 9, 2009

Synthetic Oils - Are they Worth the Cost?

Synthetic Oils - Are they Worth the Cost?

Image courtesy of outboardmotoroilblog.com

Today we hear a lot of terms thrown around when discussing motor oils. Much of the time, they are being used incorrectly.

So let’s start with mineral oil, this is the oil most of us have used in one form or another since the internal combustion engine was created. Mineral oils are distilled from crude oil as part of the refining process.

There are three categories of mineral oils; Paraffinic, Naphthenic, and Aromatic. Mineral oil can be as simple as baby oil, or as complex as today’s heavy duty motor oils. The chemistry used to create multi-grade oils and pickup and hold contaminants in solution is extremely complex.

Synthetic – Synthetic Oils can be created from many different sources and can offer many helpful characteristics such as lower friction, better high temperature performance, better stability, better sheer stability, better cold start lubrication, reduced oxidation, improved protection against thermal breakdown, less tendency to form sludge, reduces evaporative loss, potentially extends drain intervals.

There are two main categories for synthetic oils the first is:

Polyalphaolefin (PAO) an American Petroleum Institute (API) Group IV Oil Base Oil

The second is:

Synthetic esters an API Group V Base Oils ((non-PAO) synthetics, including alkylated naphthalene’s, alkylated benzenes, diesters, polyolesters, polyglycols etc.)

There is also a category called Semi-Synthetics – a mixture of petroleum and up to 30% synthetic base oils. The name Semi-Synthetic is a misnomer, oils are either Synthetic or not. If they are a mixture then if you subscribe to the theory that a chain is only as strong as its weakest link applies and the mixture will only be as good as worst performing part of the mineral oil.

The primary reasons to change motor oil are because the oil gets dirty and or because the additive package in the oil gets used up. Dirty can mean physical dirt from the environment, soot from combustion, left over combustion products and a nearly endless list of contaminants.

The additive package provides friction reduction, neutralizes acids, holds contaminants in solution, prevents oxidation, prevents corrosion, and many other vital functions. The additives are consumed or used up over time and they need to be replenished or failure will result. The method most often used is to replace the oil. This method has the advantage of taking many or hopefully most of the contaminants out of the engine with it.

Synthetic Oils may or may not have super additive packages, but eventually the oil becomes dirty to the point that it needs to be filtered or replaced and the additive package replenished or again replaced. The problem is that synthetic oil becomes contaminated long before it is “worn out” and has to be replaced to prevent damage from the contaminants. This means that often you are unable to take full advantage of the superior chemistry and characteristics of synthetic oils.

When this happens the cost disadvantage of the synthetics outweigh its other advantages.

In situations of extreme cold, high heat, high loads, extended operation at high rpm, and other related situations synthetic oils offer many superior characteristics that may improve operability, increase engine life, provide better fuel economy, and potentially improve emissions.

However for the average grocery getter or most vehicles in normal operation the added cost of synthetic motor oil is probably not justified.

View all of the Fuel School articles at: www.lcbamarketing.com and click on Technical Articles

Please post your comments, thoughts, ideas, and suggestions.

Diesel Doctor

Copyright 2009© - William Richards


Tuesday, February 10, 2009

Fuel and Water - They Don't Go Together

Fuel and Water

They don't mix and you shouldn't try to make them.


One of the more interesting characteristics that is shared by diesel, biodiesel, gasoline, and gasohol is that all these fuels are hygroscopic.

Hygroscopy is the ability of a substance to attract water molecules from the surrounding environment through either absorption or adsorption.

Some examples of this phenomenon are that Ultra-Low Sulfur Diesel (ULSD) will hold approximately 2/10 of 1% dissolved water. This may not sound like much, but if you do the numbers they show that 2/10 of 1% equals 2 gallons of water dissolved in 1000 gallons of fuel. If you work backwards, that would equal 1 gallon of water in 500 gallons of fuel, or 1 quart (32 ozs.), in 125 gallons, or 1 pint (16 ozs.), in 62.5 gallons, down to about 8 ozs. in a 30 gallon tank.

That much water can cause severe corrosion of fuel system components such as injectors, pumps, connectors, and even metal fuel tanks.

That level of water speeds the oxidation and chemical breakdown of the fuel.

That level of water is enough to encourage the growth of bacteria and fungi.

One of the most insidious characteristics of water dissolved in fuel is that the fuels ability to hold water is dependent on temperature. Simply put the warmer the fuel (up to a point) the more water it hold.

What often happens is that fuel stored for example at 60°F will absorb that 2/10% water then as the fuel in a vehicle gets colder more and more of that water is pushed out of the fuel becoming liquid water droplets.

These droplets can collect in filters and if the temperature drops below 32°F those droplets turn to ice crystals quickly plugging filters and causing other problems.

Fuel at 28°F can hold approximately 1/2 as much water as fuel at 60°F.

This means that you can have clear fuel with no liquid water at 60°F and if the temperature drops sufficiently, you can have large amounts of free water suddenly appear as the temperature drops.

To make matters worse biodiesel can pickup and hold 10 times as much water as ULSD. So adding 2% or 5% biodiesel to regular diesel can dramatically increase the level of dissolved water.

Gasoline containing Ethanol suffers the same problem.

A 10% Ethanol blend can hold 3.8 teaspoons of dissolved water at 60°F.

However if more water is added or if the temperature drops significantly this fuel suffers a problem called "Phase Separation".

In Phase Separation the dissolved (or liquid) water binds to the Ethanol and this Water/Ethanol mixture will drop out of the fuel.

This has a series of negative affects on the fuel quality and can have catastrophic effects on engines.

We will discuss more about this later.

We look forward to your comments and questions.