Wednesday, February 11, 2009

Long Term Fuel Storage

Long Term Fuel Storage


STORAGE LIFE

Under normal storage conditions diesel fuel can be expected to stay in a useable condition for:

9-12 months or longer at an ambient of 70ºF.

6-12 months at an ambient temperature higher than 85ºF.

Note: There are many factors that will affect storage life, including but not limited to:

· Ambient temperature

· Temperature variation - the wider the range, the more likely you are to have problems

· Above-Ground versus In-Ground Storage

· Dissolved water content of the fuel

· Humidity

· Quality of the fuel when added to tank

· Condition of storage tank

· Materials used in the tank and fuel piping system

As diesel gets older, fine sediment and gums will form in the fuel brought about by a chemical reaction between components in the diesel fuel with oxygen from the air. The fine sediment and gums can block fuel filters, leading to fuel starvation and the engine stopping. Frequent filter changes are then required to keep the engine going. The gums and sediments do not burn completely in the engine and this incomplete combustion can lead to carbon and soot deposits on injectors and other combustion surfaces.

The expected life of a diesel fuel can be indicated by the oxidation stability test ASTM D2276. The test measures how much gum and sediment will be deposited after keeping the fuel at 120°C in the presence of oxygen for 16 hours. It roughly corresponds to one year storage at 25°C. A result of less than 20mg/L of sediment and gum after the test is considered acceptable for normal diesel.


ACCELERATED AGING

The aging process can be accelerated by the following conditions:

• Contact with zinc, copper or metal alloys containing them. These metals will quickly react with diesel fuel to form unstable compounds.

• The presence of water. Water allows the growth of fungus and bacteria, these produce natural by-products such as organic acids which make the fuel unstable.

• Exposure to high temperatures.

• Exposure to dust and dirt which contain trace elements that can destabilize the fuel, such as copper and zinc.

• Fuel composition. Some components in diesel fuel naturally age quickly.


PROLONGING THE STORAGE LIFE

Prolonging the storage life is achieved by removing or controlling the conditions described in the previous section. Important measures to take are as follows:

• Ensure that the fuel is not in contact with any surfaces containing zinc or copper or compounds containing those metals (e.g. brass). If those metals are present then a metal deactivator additive may help.

• Establish a regular fuel maintenance program to ensure that water and dirt is removed from storage tanks. This will also remove any chance for fungus to grow.

• Water should be drained from the storage tanks weekly. The frequency can be extended if the tank shows no tendency to collect water but should be done at least monthly.

• Tanks should be kept full to reduce the space for water to condense, maintaining tanks half full increases the water build up and promotes corrosion in the top half of the tank. Most water will come from condensation as the tank breathes. The rate at which water collects will depend on local climate and will be higher in hot humid coastal areas.

• Tanks if possible should have a well defined low point where water will collect and can be drained. For example, cone down bottoms.

• Establish a system for filtering the contents of the main storage tank through a recirculating filter system. This can be made automatic and will reduce the potential for problems by removing sediment and gums. The filters should be checked and changed at regular intervals. When the filter change interval reaches a certain frequency then the fuel should be changed over.

• Tanks should be emptied and cleaned at least once every 10 years, or more frequently if there is a major contamination.

• Ensure that the fuel supplied conforms to a recognized specification to ensure the fuel matches the winter cloud point for the area to avoid filter blocking by wax drop out in cold weather.

• Always purchase fuel to replenish stocks in the winter season November - March. This will help to ensure that the fuel will not cause wax problems whatever season it is used.

• Obtain assurances from the supplier that all components are fully refined to promote stability.

• Establish a monitoring program whereby samples are taken at regular intervals to monitor the condition of the fuel. The samples can be examined at the site visually for evidence of haziness, sediment, darkening or sent to a laboratory for testing.

• Regularly turn the fuel over. If possible, plan the fuel usage so that it will all be used within 1-5 years and replaced with fresh fuel.


ADDITIVES TO IMPROVE STORAGE LIFE

The following additives can improve fuel storage life:

• Metal deactivators. These work by stopping copper, zinc and other reactive metals from reacting with the fuel.

• Fungicides/Biocides. These work by stopping fungus and bacteria from growing in the fuel and so prolong the life of the fuel. They are only effective on fungus and bacteria and will not stop other oxidation reactions from taking place. They are normally active at the water fuel interface where the fungus and bacteria grow. If fungus is present then a kill dose is required. Otherwise a maintenance dose is used to stop fungus growing.

The disadvantages of biocides are:

• Handling and mixing is hazardous because they are poisons.

• When using a kill dose, it is important to remember that killing the fungus can lead to a buildup of dead matter which will block filters and also cause the fuel to oxidize.

• Ideally, the fungus should be killed and then the tank emptied and drained out.

• Maintenance doses are effective but no more so than regular water draining and or the use of a Water Dispersant.

• Disposal of water bottoms requires special handling with due regard to the environment.

• Anti-Oxidants. These work by stopping the oxidation processes from taking place. They prevent the fuel oxidizing and reduce the formation of sediment and gum.

As always, your questions and comments are welcomed and encouraged

5 comments:

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